Chirped-pulse mmW spectroscopy in uniform flows
CPUF combines chirped-pulse Fourier-Transform mmWave rotational spectroscopy with uniform supersonic flows as a novel probe of dynamics and kinetics at low temperature. The power of the combination arises from the cooling of the nascent products to low and uniform temperature in the flow coupled with the nearly universal and quantitative detection my micro- and mmWave chirped-pulse spectroscopy.
Ranil M. Gurusinghe†, Nureshan Dias†, Ritter Krueger, and Arthur G. Suits*, “Uniform Supersonic Flow Sampling for Detection by Chirped-Pulse Rotational Spectroscopy,” J. Chem. Phys. (in press) (2021) https://doi.org/10.1063/5.0073527
Ranil M. Gurusinghe, Nureshan Dias, Alexander Mebel, and Arthur G. Suits*,
“Radical-Radical Reaction Dynamics Probed using mmW Spectroscopy: Propargyl + NH2/ND2,” J. Phys. Chem. Lett. (2021) in press. DOI: 10.1021/acs.jpclett.1c03813
N. Dias, B. Joalland, N. M. Ariyasingha, A. G. Suits and B. M. Broderick, “Direct versus Indirect Photodissociation of Isoxazole from Product Branching: A Chirped-Pulse Fourier Transform mm-wave Spectroscopy/Pulsed Uniform Flow Investigation,” J. Phys. Chem. A, (2019) DOI: 10.1021/acs.jpca.8b04713